Rise in unregulated ozone-depleting chemical

| Cleanrooms and Contamination Control

3D model of dichloromethane molecule

The University of Leeds has identified an increase in the use of dichloromethane gas, contributing to the destruction of the ozone layer.

Chemicals that are designed to protect the Ozone Layer – and are therefore not controlled by a United Nations treaty – are contributing to ozone depletion. An alarming new study, published in Nature Geoscience, says that scientists also report the atmospheric abundance of one of these “very short-lived substances” (VSLS) – dichloromethane – is growing rapidly.

Study lead author Dr Ryan Hossaini, from the School of Earth and Environment at the University of Leeds, said: “VSLS can have both natural and industrial sources. Industrial production of VSLS is not controlled by the United Nations Montreal Protocol because historically these chemicals have contributed little to ozone depletion.

“But we have identified now that one of these chemicals is increasing rapidly and, if this increase is allowed to continue, it could offset some of the benefits to the Ozone Layer provided by the Montreal Protocol.”

In the study, researchers have used a 3D computer model of the atmosphere to determine the impact of VSLS on ozone and climate. Measurements of VSLS in the atmosphere over the past two decades, provided by collaborators from the National Oceanic and Atmospheric Administration (NOAA) in the United States, were also analysed. These measurements revealed a rapid increase in atmospheric concentrations of dichloromethane, a man-made VSLS used in a range of industrial processes.

Professor Martyn Chipperfield, says: “We need to continue monitoring the atmospheric abundance of these gases and determine their sources. At present, the long-term recovery of the Ozone Layer from the effects of CFCs is still on track, but the presence of increasing dichloromethane will lead to uncertainty in our future predictions of ozone and climate.”

The researchers found that while the amount of ozone depletion arising from VSLS in the atmosphere today is small compared to that caused by longer-lived gases, such as CFCs, VSLS-driven ozone depletion was found to be almost four times more efficient at influencing climate.

“Due to their short atmospheric lifetimes, VSLS break down and destroy ozone in the lowermost part of the stratosphere. This is important, as a molecule of ozone lost in this region has a far larger impact on climate than a molecule destroyed at higher altitudes by longer-lived gases,” added Hossaini. “It is uncertain what is driving this growth. However, it could be partly due to the fact that dichloromethane is used in the manufacturing process of some HFCs, the ‘ozone-friendly’ gases which were developed to replace CFCs. This would mean, ironically, that production of ozone-friendly chemicals is actually releasing some ozone-destroying gases into the atmosphere.”

The researchers have also separated out natural sources of VSLS – such as seaweed in the ocean – and those released due to human activity – such as industrial processes – in order to determine the relative importance of each.

At present, naturally-emitted VSLS account for around 90% of the total ozone loss caused by VSLS in the lower stratosphere. However, the contribution from man-made VSLS compounds is increasing and appears set to increase further in coming years.

NOAA’s Dr Stephen Montzka from the NOAA added: “The increases observed for dichloromethane are striking and unexpected; concentrations had been decreasing slowly in the late 1990s, but since then have increased by about a factor of two at sites throughout the globe.”

Substitutes for dichloromethane

Dichloromethane (otherwise known as methylene chloride) is used as a CFC replacement in the production of polyurethane flexible slab, and as an aerosol propellant.

Many other alternatives now exist for flexible slab construction, including extended range polyols, carbon dioxide/water, softening agents, acetone, increased density, HCFC-141b, pentane, and other alternative technologies such as accelerated cooling and variable pressure. The long term will probably see the use of injected carbon dioxide and alternative technologies.

In the era of CFCs, methyl chloroform (1,1,1 trichloroethane) was usually the solvent in aerosol applications, but some CFC-113 has also been used. Most of these applications are now reformulated , but with the exception of water, dichloromethane, and some HCFCs and non-ozone-depleting chlorinated solvents such as trichloroethylene and perchloroethylene, all of the other alternatives are more flammable.

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